Natural Chemistry II Follow Chem242
Week three Alkene synthesis
Dehydrohalogenation (E2): Draw the major products
Acid-catalyzed dehydration of alcohols (E1)
Draw ALL potential products and point out the major one.
2-bromo-2-methylpentane
NaOCH2CH3
CH2CH3OH
2-bromo-2-methylpentane
NaOC(CH3)three
HOC(CH3)three
Br NaOCH2CH3
CH2CH3OH
H
Br
D
CH3
H
H
NaOCH2CH3
CH2CH3OH
H
Br
H
CH3
H
D
NaOCH2CH3
CH2CH3OH
CH3
Br
D
H
H
H
NaOCH2CH3
CH2CH3OH
OH
H2SO4
warmth
OH
H3PO4
warmth
———
Natural Chemistry II Follow Chem242 Week three Synthesis of Alkenes
Draw the major products of dehydrohalogenation (E2).
Alcohol dehydration catalyzed by an acid (E1)
Draw EVERY POSSIBLE PRODUCT and point out the most vital one.
2-bromo-2-methylpentane
NaOCH2CH3
CH2CH3OH
2-bromo-2-methylpentane
NaOC(CH3)three
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HOC(CH3)three
Br NaOCH2CH3
CH2CH3OH
H
Br
D
CH3
H
H
NaOCH2CH3
CH2CH3OH
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H
Br
H
CH3
H
D
NaOCH2CH3
CH2CH3OH
CH3
Br
D
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H
H
H
NaOCH2CH3
CH2CH3OH
OH
H2SO4
warmth
OH
H3PO4
warmth
